| Pos |
No |
Pilote |
Voiture |
Temps |
| 1 | 301 | John Whitmore/Frank Gardner | Ford Lotus Cortina | 4:46,1 |
| 2 | 100 | Eugen Böhringer/Dieter Glemser | Mercedes 300 SE | 4:48,4 |
| 3 | 205 | Leo Cella/Marco Crosina | Lancia Flavia Sport Zagato | 4:54,5 |
| 4 | 204 | Hubert Hahne/Rauno Aaltonen | BMW 1800 TI | 4:55,0 |
| 5 | 300 | Henry Taylor/Peter Harper | Ford Lotus Cortina | 4:55,8 |
| 6 | 102 | Robert Crevits/Taf Gosselin | Mercedes 300 SE | 4:56,0 |
| 7 | 101 | Herbert Linge/Peter Lang | Mercedes 300 SE | 5:01,1 |
| 8 | 203 | Eppelein/Walter | BMW 1800 TI | 5:03,5 |
| 9 | 103 | Giancarlo Galimberti/Carlo Facetti | Alfa Romeo 2600 Sprint | 5:04,3 |
| 10 | 311 | Lucien Bianchi/Fernand Masoero | Alfa Romeo Giulia TI Super | 5:04,7 |
| 11 | 207 | René Trautmann/Bruno Deserti | Lancia Flavia Sport Zagato | 5:05,4 |
| 12 | | Giorgio Pianta/Luciano Massoni | Lancia Flaminia | 5:05,8 |
| 13 | 208 | Pascal Ickx/Georges Harris | Lancia Flaminia | 5:06,1 |
| 14 | 303 | Tony Hegbourne/Roy Pierpoint | Ford Cortina GT | 5:06,9 |
| 15 | 307 | Andrea Vianini/Gianni Balzarini | Alfa Romeo Giulia TI Super | 5:06,9 |
| 16 | 104 | Jean Rolland/Jean-Jacques Pagnon | Alfa Romeo 2600 Sprint | 5:08,3 |
| 17 | 206 | Piero Frescobaldi/Ferdinando Frescobaldi | Lancia Flavia Sport Zagato | 5:10,4 |
| 18 | | Ada Pace/Claudine Bouchet | Lancia Flaminia | inconnu |
| 19 | 308 | Francesco de Leonibus/Riccardo di Bona | Alfa Romeo Giulia TI Super | 5:18,0 |
| 20 | | Claude Dubois/Yves Deprez | Morris Mini Cooper S | 5:19,3 |
| 21 | 304 | Jacky Ickx/Teddy Pilette | Ford Lotus Cortina | 5:20,1 |
| 22 | 404 | Gerhard Bodmer/Dieter Schmid | Glas 1204 TS | 5:22,7 |
| 23 | 302 | Gilbert Stapelaere/Meuwissen | Ford Lotus Cortina | 5:24,1 |
| 24 | | Jacques Patte/Dany Wauters | Volvo 122 S | 5:24,6 |
| 25 | 305 | Kelly/Ted Lund/Alan Mann | Ford Lotus Cortina | 5:25,5 |
| 26 | | Philippe De Barsy/Carl Smet | Morris Mini Cooper S | 5:29,2 |
| 27 | 210 | Georges Hacquin/Henri Quernette | Volvo 122 S | 5.29,7 |
| 28 | 209 | JP Ackermans/'Caddy' | Volvo 122 S | 5:31,2 |
| 29 | 211 | Freddy Rousselle/Romedenne | Volvo 122 S | 5:33,5 |
| 30 | 309 | Andrea de Adamich/Gino Munaron | Alfa Romeo Giulia TI Super | 5:35,0 |
| 31 | 202 | Jean Demortier/Vittel | Citroën DS 19 | 5:37,0 |
| 32 | 201 | Guy Verrier/Alain Bertaut | Citroën DS 19 | 5:37,5 |
| 33 | 310 | Gerard Sevaux/Georges Naneix | Alfa Romeo Giulia TI Super | 5:38,3 |
| 34 | 405 | Georges Lambrechts/Charles Mombaerts | Glas 1204 TS | 5:39,4 |
| 35 | 200 | Jean-Claude Ogier/Patrick Vanson | Citroën DS 19 | 5:40,0 |
| 36 | | Emile Holvoet/Hugo Schumacher | DKW F12 | 5:43,2 |
| 37 | 403 | Günther Isenbügel/Helmut Rathjen | Glas 1204 TS | 5:46,2 |
| 38 | | Hughes de Fierlant/Maurice Damseaux | Austin Mini Cooper S | 5:47,3 |
| 39 | | Elizabeth Jones/Harry Ratcliffe | Morris Mini Cooper S | 5:48,2 |
| 40 | 504 | Julien Vernaeve/Paddy Hopkirk | Morris Mini Cooper S | 5:50,8 |
| 41 | 507 | Nicolas Koob/Raymond Schweich | Morris Mini Cooper S | 5:51,0 |
| 42 | | Maurice Vandenbruwaene/André Buge | Volvo 122 S | 5:.56,1 |
| 43 | 306 | Claudio Castellano/Jack Crawley | Alfa Romeo Giulia TI Super | 5:58,6 |
| 44 | 506 | T'Kint/Paul Lucas | Morris Mini Cooper S | 5:58,9 |
| 45 | 508 | Jean-Marie Sachet/Claude Levasseur | Alpine A 108 | 6:02,9 |
| 46 | 316 | Jacques Thenaers/Jean-Pierre Gaban | VW 1500 S | 6:05,2 |
| 47 | 216 | Roland Hanser/Armsbuster | Peugeot 404 | 6:10,2 |
| 48 | 313 | Guy Sanders/Paul Nokin | VW 1500 S | 6:11,1 |
| 49 | 315 | Ben Pon/C.De Moffarts | VW 1500 S | 6:11,7 |
| 50 | 314 | Wim De Jonghe/Eddie Meert | VW 1500 S | 6:12,5 |
| 51 | 501 | Chris Tuerlinx/Martin Baeten | Opel Kadett | 6:19,5 |
| 52 | | 'Pat' Gautot/Bill Blydenstein | Opel Kadett | 6:38,1 |
| 53 | 510 | Jean-Marie Lagae/Jean Carpentier | NSU Prinz 1000 | 6:49,5 |
| 54 | 408 | Xavier Boulanger/Gilmont | Morris Mini Cooper S | 6:51,3 |
| 55 | 502 | Nederth/Eggerth | Opel Kadett | 7:15,2 |
|
24 Heures de Spa-Francorchamps 1964