| No |
Pilote |
Team |
Voiture |
| 1 | Roy Pierpoint/Doug Serrurier | Pierpoint | Lola T70 Ford |
| 2 | Peter Sutcliffe/John Love | Petr Sutcliffe | Ford P40 |
| 3 | David Piper/Richard Attwood | David Piper Auto Racing | Ferrari 365 P2/P3 |
| 4 | Willy Mairesse/Jean Beurlys | Ecurie Francorchamps | Ferrari 365 P2/3 |
| 5 | Eldé/Jacky Ickx | Ecurie Francorchamps | Ferrari 275 LM |
| 6 | Peter Clarke/Rollo Fielding | P. Clarke | Ferrari 275 LM |
| 7 | Bob Anderson/Mike Hailwood | Bernard White Racing Team | Ferrari 275 LM |
| 8 | David Hobbs/Mike Spence | Bernard White Racing Team | Ford GT40 |
| 9 | Ed Nelson/Colin Crabbe | E. S. Nelson | Ford GT40 |
| 10 | Mike De Udy/Peter de Klerk | Porsche Great Britain | Porsche Carrera 6 |
| 11 | Ben Pon/Gijs van Lennep | Racing Team Holland | Porsche Carrera 6 |
| 12 | Luki Botha/Dawie Gous | L. J. Botha | Elva - Porsche |
| 14 | Richard Jute/John Whitehead | Ecurie Aquila | GSM Dart Ford |
| 15 | John Truter/Neville Smith | Bramhill Service Station | GSM Dart Ford |
| 16 | Clive van Beuren/Steve Mellet | Ecurie Tomahawk | Porsche 718 RS |
| 17 | Keith Berrington-Smith/Tony Jefferies | Team Thompson Bros. | Lotus 23 Alfa Romeo |
| 18 | John Haycock/Denis Joubert | J. Haycock | Lotus 23 Ford |
| 19 | Jack Holme/Brian Wheble | J. Holme | Lotus Elan |
| 20 | Joss Viljoen/George van Straaten | J. Viljoen | Elfin Mallala Ford |
| 21 | Eric van der Meden/Peter Shekleton | Shekleton Motors | GSM Dart Ford |
| 23 | Louis Cloete/Alec Kirstein | Philip Robinson Motors | Ford Cortina GT |
| 24 | Basil Greenstone/Gordon Littleford | Basil Green Motors | Ford Anglia Super |
| 25 | Geoff Mortimer/Roger Ramsayer | Team Renault & Alconi Devel | Renault R8 |
| 26 | Basil van Rooyen/Chappie Wicks | Team Thompson Bros. | Alfa Romeo GTA |
| 27 | Scamp Porter/Eric Adler | Team Lawson | Renault R8 Gordini |
| 28 | Fred Cowell/John Fritelli | J. F. Cowell | Alfa Romeo Giulia Sprint |
| 29 | Mervyn Grevler/Tony Woodley | Superformance Racing Team | Alfa Romeo Giulia Sprint |
| 30 | Mario Lupini/Chris van den Heever | Superformance Racing Team | Alfa Romeo Super |
| 31 | John Myers/Spencer Schultze | Team Renault | Renault R8 Gordini |
| 32 | George Armstrong/Luigi Viglietti | Team A & G | Austin Cooper S |
| 33 | Phil Cadman/Frank Rundel | P. T. H. Cadman | M.G.B. |
| 35 | Nolly Limberis/Garth McGillewie | Power Filling Station Racing | Morris Cooper S |
| 36 | Ian Houliston/Peter Sissons | Ian Houliston | Morris Cooper S |
| 38 | Colin Burford/Phil Porter | Team Renault & Alconi Devel | Renault R10 |
| 39 | Franck Wingels/Dirk Marais | Team Lawson | Volvo 122S |
| 40 | Arnold Chatz/Dave Clapham | Team Lawson | Volvo 122S |
9 Heures de Kyalami 1966